Proof of the Formation of 2, 4, 6-Trimelaminyl-s-triazine

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Degradation of terbutylazine (2-chloro-4-ethylamino-6-terbutylamino-1,3,5-triazine), deisopropyl atrazine (2-amino-4-chloro-6-ethylamino-1,3,5-triazine), and chlorinated dimethoxy triazine (2-chloro-4,6-dimethoxy-1,3,5-triazine) by zero valent iron and electrochemical reduction.

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6-(4-Meth­oxy­phen­yl)-1,3,5-triazine-2,4-diamine

In the title compound, C(10)H(11)N(5)O, the triazine ring forms a dihedral angle of 10.37 (4)° with the benzene ring. In the crystal, adjacent mol-ecules are linked by a pair of N-H⋯N hydrogen bonds, forming an inversion dimer with an R(2) (2)(8) ring motif. The dimers are further connected via N-H⋯O and N-H⋯N hydrogen bonds, resulting in a three-dimensional network.

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ژورنال

عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan

سال: 1968

ISSN: 0023-2734,2185-0860

DOI: 10.1246/nikkashi1898.71.5_727